Product ID:ALODINE 1201
MSDS Date:11/05/1992
FSC:8030
NIIN:00-065-0957
MSDS Number: BTZTV

HENKEL CORPORATION

32100 STEPHENSON HWY
MADISON HEIGHTS, MI 48071
US

Emergency Phone: 517-263-9430/ 800-424-9300 CHEMTREC

Info Phone: 313-583-9300

Preparer: S WHITNEY

Cage: DO342

RALRUBE INC.

FARMINGTON HILLS, MI 48331 US

Telephone: 248-661-0260, FAX 248-661-3941

Cage: 6X798

CHROMIC ACID (SARA III)

CAS: 7738-94-5

RTECS: GB2450000

Fraction By Weight: 1%

OSHA PEL 0.1 MG/M3

ACGIH TLV: 0.05 MG/M3

EPA Report Quantity: 10 LBS

DOT Report Quantity: 10 LBS

POTASSIUM FERRICYANIDE

CAS: 13746-66-2

RTECS: LJ8225000

Fraction By Weight: 0.1-1%

HYDROFLUORIC ACID (SARA III) (EXTREMELY HAZARDOUS

CAS: 7664-39-3

RTECS: MW7875000

Fraction By Weight: 0.1-1%

OSHA PEL C 3 PPM (AS F)

ACGIH TLV: C3PPM(AS F);STEL6PPM

EPA Report Quantity: 100 LBS

DOT Report Quantity: 100 LBS

Health Hazards Acute and Chronic:EYE: SEVERE IRRITATION. SKIN:
IRRITATION. AABSORPTION: CHROMIC ACID MAY BE ABSORBED THROUGH SKIN,
EXPECIALLY IF SKIN DMAGED. FATAL KIDNEY DAMAGE REPORTED.
INHALATION: IRRITATE, MAY BURN MUCOUS MEMBRAN ES IF PROLONGED.
Explanation of Carcinogenicity:EXPECTED THAT CHROMIC ACID MAY INCREASE
INCIDENCE OF LUNG CANCER (ANIMAL LABORATORY STUDIES).
Effects of Overexposure:CHRONIC: PROLONGED OR REPEATED CONTACT MAY
CAUSE CHROME SORES. LONG-TERM EXPOSURE CAN CAUSE LIVER DAMAGE,
KIDNEY DAMAGE AND DERMATITIS. PROLONGED OR REPEATED INHALATION OF
MIST MAY CAUSE ULCERATION AN D PERFORATION OF THE NASAL SEPTUM.
Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN DISORDERS

First Aid:EYE: IMMED FLUSH IN RUNNING WATER 15 MINUTES HOLDING EYELIDS
APART. GET MED AID. SKIN: IMMED FLUSH W/WATER 15 MINUTES WHILE
REMOVING CONTAM CLOTHING. SOAK AREA FOR 1 HR IN ICED SOLUTION
(0.13%) OF ZEP HRIN CHLORIDE (30CC OF 17% CONCENTRATE PER GAL ICED
DISTILLED WATER). GET MED AID. INHAL: REMOVE TO FRESH AIR. IF
BREATHING DIFFICULT, GIVE OXYGEN. GET MED AID. INGEST: DON'T INDUCE
VOMIT. GET MED AID

Extinguishing Media:AS REQUIRED TO EXTINGUISH SURROUNDING FIRE.
Fire Fighting Procedures:WEAR POSITIVE PRESSURE SELF-CONTAINED
BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING.
Unusual Fire/Explosion Hazard:PRESENTS NO HAZARD IN LIQUID FORM,
HOWEVER CHEMICAL CONTAINS STRONG OXIDIZERS WHICH MAY SUPPLY OXYGEN
WHEN DRY.

Spill Release Procedures:WEAR PROTECTIVE CLOTHING. ABSORB OR OTHERWISE
COLLECT SPILL AND STORE IN POLYETHYLENE OR POLYETHENE-LINED STEEL
CONTAINER.

Handling and Storage Precautions:DO NOT GET IN EYES, ON SKIN OR ON
CLOTHING. CLOTHING OR OTHER COMBUSTIBLE MATERIAL WET WITH THIS
MATERIAL AND ALLOWED TO DRY MAY BE BECOME FLAMMABLE.
Other Precautions:WASH THOROUGHLY AFTER HANDLING. FOR INDUSTRIAL USE
ONLY.

Respiratory Protection:NOT NORMALLY REQUIRED. IF SIGNIFICANT VAPORS OR
MIST ARE GENERATED, USE A NIOSH APPROVED RESPIRATOR
Ventilation:USE WITH ADEQUATE VENTILATION. PROVIDE GENERAL AND LOCAL
EXHAUST VENTILATION.
Protective Gloves:CHEMICAL RESISTANT GLOVES
Eye Protection:CHEMICAL GOGGLES OR FACE SHIELD.
Other Protective Equipment:EYE WASH AND EMERGENCY SHOWER SHOULD BE IN
CLOSE PROXIMITY. APPROPRIATE PROTECTIVE CLOTHING SUCH AS APRONS,
BOOTS, ETC.
Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING.
Supplemental Safety and Health

HCC:C1
Boiling Pt:B.P. Text:212F,100C
Spec Gravity:ABOUT 1
pH:<2
Solubility in Water:COMPLETE
Appearance and Odor:AMBER LIQUID; NO ODOR

Stability Indicator/Materials to Avoid:YES
KEEP SEPARATE FROM ALKALIES.
Stability Condition to Avoid:NONE
Hazardous Decomposition Products:CONTAINS <1% POTASSIUM
FERRICYANIDE.HEATED TO DECOMP/CONTACT W/STRONG ACID POTASSIUM
FERRICYANIDE CAN EMIT CYANIDE FUMES

Waste Disposal Methods:THIS CHEMICAL CONTAINS CHROMIUM COMPOUNDS AND
FLUORIDE COMPOUNDS. WASTE TREATMENT AND NEUTRALIZATION MAY BE
REQUIRED PRIOR TO DISCHARGE TO A SEWER. DISPOSE OF IN COMPLIANCE
WITH ALL APPLICABLE FEDERAL , STATE, AND LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.